Pre-heat oven to 350°F. Line a 9 inch square cake pan with a piece of parchment paper, leaving a bit of an overhang (so you can pull out the cake after it's baked). Lightly butter the two sides of the pan not covered by parchment.
In a large bowl, whisk together sugar, flour ¾ cup PLUS 2 tablespoons), unsweetened cocoa powder, baking powder, baking soda and salt.
1 cup granulated sugar, ¾ cup all purpose flour, 2 tablespoons all purpose flour, 6 tablespoons unsweetened cocoa powder, ¾ teaspoon baking powder, ¾ teaspoon baking soda, ½ teaspoon fine sea salt
Whisk together, egg, milk, oil and vanilla until combined and stir into the dry ingredients.
1 large egg, ½ cup milk, ¼ cup vegetable oil, 1 teaspoon vanilla extract
Add hot water (or hot coffee) and blend or whisk until fully incorporated. The batter will be very thin, this is right.
½ cup hot water
Pour batter into prepared pan and bake 22 to 28 minutes, or until a toothpick inserted into the center of the cake come out clean.
While the cake cools, use a pastry brush to brush the top of the cake with the Grand Marnier.
2 tablespoons Grand Marnier